Kinetic Extraction of Moringa oleifera Leaves using the Microwave Assisted Extraction (MAE) Method
Kinetic Extraction of Moringa oleifera Leaves using the Microwave Assisted Extraction (MAE) Method
Ghina Shofiah Adibah Khoirunnisa
Department of Chemical Engineering, Faculty of Engineering, Jember University, Indonesia
Reinaldi Rizky Pratama
Department of Chemical Engineering, Faculty of Engineering, Jember University, Indonesia
Ditta Kharisma Yolanda Putri
Department of Chemical Engineering, Faculty of Engineering, Jember University, Indonesia
Helda Wika Amini
Department of Chemical Engineering, Faculty of Engineering, Jember University, Indonesia
Boy Arief Fachri
Department of Chemical Engineering, Faculty of Engineering, Jember University, Indonesia
DOI: https://doi.org/10.19184/jobc.v4i2.1379
ABSTRACT
Moringa oleifera leaves are known for their distinctive leaf shape and offer numerous health and nutritional benefits. They are rich in vitamins, minerals, proteins, and bioactive compounds and possess antioxidant and anti-inflammatory properties. This study aimed to explore the extraction process, identify the presence of tannin compounds in Moringa leaves, and determine the appropriate kinetic model for the extraction of Moringa leaf extract using the Microwave-Assisted Extraction (MAE) method. The extraction was performed using 96% ethanol as the solvent and the MAE technique, which is known to enhance extraction efficiency. Variables such as power (150 watts), a material-to-solvent ratio of 1:15 (b/v), and extraction times of 2, 4, 6, 8, and 10 minutes were tested. The results indicated that the highest yield was achieved after 10 minutes, with a value of 10.25%. The extraction time was extended at most 10 minutes due to time limitations and diminishing returns as the extraction time increased. The study concluded that the second-order kinetic model (R² = 0.9897) was the most suitable for describing the extraction of tannin compounds from Moringa leaves, outperforming the first-order model with a value closer to 1.
Keywords: extraction, Moringa oleifera, flavonoids, and microwave-assisted extraction
REFERENCES
[1] A. T. O. Rivai. 2020. Identifikasi Senyawa yang Terkandung pada Ekstrak Daun Kelor (Moringa oleifera).Universitas Islam Negeri Alauddin Makassar. Indonesian Journal of Fundamental Sciences 6(2).
[2] C. Angelin, et al. 2021. Peningkatan Nilai Gizi Produk Pangan dengan Penambahan Bubuk Daun Kelor(Moringa Oleofera L.): Riview. Fakultas Teknobiologi, Universitas Atma Jaya, Yogyakarta. Jurnal Agroteknologi: 15(1).
[3] Rohyani, et al. 2015. Kandungan Fitokimia beberapa Jenis Tumbuhan Lokal yang Dimanfaatkan SebagaiBahan Baku Obat di Pulau Lombok. Pros Sem Nas Masy Biodiv Indon 1(2): 388-391.
[4] Warnis, et al. 2020. Isolasi dan Identifikasi Senyawa Flavonoid dari Daun Kelor (Moringa Oleofera L.) dan UjiAktivitas Sebagai Antioksidan. Program Strata I Jurusan Kimia pada Universitas Negeri Semarang, Under Graduates Thesis, Universitas Negeri Semarang.
[5] Zhang, W., & Duan, X. 2020. Advances in the extraction of natural products: pharmaceuticals, nutraceuticals, and functional foods. Food and Bioproducts Processing Journal, 120: 233-250.
[6] Apriyati, et al. 2022. Pengaruh Lama Waktu Maserasi Terhadap Kadar Senyawa dan Antioksidan Ekstrak Daun Kelor (Moringa Oleofera L.). Jurnal Teknologi Pangan 16(1): 116-123.
[7] Fakhruzy et al. 2020. Optimalisasi Metode Maserasi untuk Ekstrak Tanin Rendemen Tinggi. FakultasKehutanan, Universitas Muhammadiyah, Sumatera Barat. Menara Ilmu 14(2).
[8] Chemat et al. 2011. Applications of ultrasound in food technology: Processing, preservation, and extraction. Ultrasonics Sonochemistry, 18(4), 813-835.
[9] I. Cahyana dkk. 2021. Ekstraksi Senyawa Tanin dari Kulit Bawang Putih (Allium Sativum L.). Jurusan Teknik Kimia, Fakultas Teknik, Universitas Wahid Hasyim.
[10] Naraswanik, P. K. 2021. Isolasi dan Identifikasi Senyawa Flavonoid Daun Kelor (Moringa Oleofera L.)dengan Metode Ekstraksi Ultrasonik. Jurnal Teknologi dan Sains 10(6).
[11] K. Sin et al. 2014. Microwave-Assisted Extraction of Phenolic Compounds from Moringa oleifera Lam. LeavesUsing Response Surface Methodology as Optimization Tool. Philip Agric Scientist 97(1): 36-42.
[12] H. Niawanti, et al. 2021. Ekstraksi Tanin dari Daun Psidium Guajava Menggunakan Metode Soxhlet.Program Studi Teknik Kimia, Fakultas Teknik, Universitas Mulawarman, Samarinda. Jurnal Teknologi Separasi 7(2): 353-359.
[13] H. Niawanti & N. P. Putri. Pemilihan Jenis Pelarut Pada Ekstraksi Tanin dari Daun Avverhoa Bilimbi denganMetode Soxhlet. Program Studi Teknik Kimia, Fakultas Teknik, Universitas Mulawarman, Samarinda. Jurnal Integrasi Proses 9(2): 15.
[14] T. M. Putri, et al. 2020. Ekstraksi Senyawa Tanin dari Mangrove (Brugueria Gymnorrhiza)Menggunakan Pelarut Aquades dan Etanol Sebagai Pewarna Alami dan Penguat Serat Kain. Fakultas IlmuPengetahuan dan Matematika, Universitas PGRI Banyuwangi (UNIBA), Banyuwangi. Jurnal CrystalPublikasi Penelitian Kimia dan Terapan 2(1): 13-24.
[15] Iriany et al. 2017. Ekstraksi Tanin dari Kulit Akasia dengan Menggunakan Microwave: Pengaruh Daya, Waktu,dan Jenis Pelarut. Departemen Teknik Kimia, Fakultas Teknik, Pusat Unggulan ProdukNatural BerbasisTeknologi, Sumatera. Jurnal Teknik Kimia USU 6(3).
[16] H. R. Hakim, et al. 2020. Efektifitas Konsentrasi Pelarut Etanol Pada Proses Eksraksi Moringa OliferaMenggunakan Metode Microwave Assisted Extraction (MAE). Jurusan Teknik Kimia, Fakultas TeknologiIndustri, Institut Teknologi Adhi Tama Surabaya.
[17] Handayani, et al. 2020. Analisis Kualitatif dan Kuantitatif Metabolit Sekunder Ekstrak Biji Kelor (Moringaoleifera Lam.) dengan Metode Spektrofotometri UV-Vis. Kovalen: Jurnal Riset Kimia 6(2): 230-238.
[18] Mandal, V., Mohan, Y. and Hemalatha, S. 2017. Microwave Assisted Extraction-An Innovative and Promissing Extraction Tool for Medicinal Plant Research. Pharmacognosy Reviews 1(1):18.
[19] H.S. Kusuma & M. Mahfud. 2018. Kinetic Studies on Extraction of Essential Oil from Sandalwood (SantalumAlbum) by Microwave Air-Hydrodistillation Method. Department of Chemical Engineering. Institut TeknologiSepuluh Nopember, Surabaya. Alexandria Engineering Journal 57:1163-1172.
[20] Tandi. J, et al. 2020. Analisis Kualitatif dan Kuantitatif Metabolit Sekunder Ekstrak Etanol BUah Okra(Abelmoschus esculentus L. Moench) dengan Metode Spektrofotometri UV-Vis. Program Studi S1 Farmasi,STIFA Pelita Mas Palu. KOVALEN:Jurnal Riset Kimia 6(1):74-80.
[21] Wayan. I. D. P. P. 2016. Identifikasi Senyawa Kimia Ekstra Etanol Daun Kelor (Moringa oleifera L) di Bali.Fakultas Kedokteran Hewan, Universitas Udayana. Indonesia Medicus Veterinus 5(5):464-473.
[22] Isdiyanti, S.I, et al. 2021. Ekstraksi Flavonoid dari Daun Kersen (Muntinga calabura l) Menggunakan pelarutEtanol dengan Metode MAE (Miicrowave Assisted Extraction) dan UAE (Ultrasonic Assisted Extraction). JurusanTeknik Kimia, Universitas Wahid Hasyim Semarang. Inovasi Teknik Kimia 6(2):105-109.
[23] Yulia., et al. 2022. Skrinning Fitokimia dan Penentuan Kadar Flavonoid Daun Kelor (Moringa Oleifera L.)Desa Dolok Sinumbah dan Raja Maligas Kecamatan Hutabanyu Raja). KLOROFIL 6(1): 49-56
[24] Febriani, et al. 2015. Karakterisasi Simplisia dan Ekstrak Etanol Daun Sirsak (Annona Muricata Linn). ProdiFarmasi, Fakultas MIPA, Unisba.
[25] Rifkia, V., & Revina, R. 2023. Pengaruh Variasi Bahan: Pelarut dan Lama Ekstraksi Ultrasonik dari EkstrakDaun Kelor terhadap Rendemen dan Kadar Total Fenol. Jurnal Farmasi Indonesia, 15(1): 94–100.
[26] M. N. Morshed, et al. 2016. Aqueous and Solvent Extraction of Natural Colorants from Tagetes Erecta L.,Lawsonia Inermis, Rosa L for Coloration of Cellulosic Substrates. Flavour and Fragrance Journal,16(2):34-39.
[27] Z. Masum, et al. 2021. “Kinetics study of microwave hydrodestillation (MHD) fresh and dried Cymbopogon Nardusleaves,”AIP Conference Proceedings Journal.
[28] Zhu, F., Zhang, M., & Xu, B. (2018). Extraction of tannins from different plant species: Influence of extractionmethods and conditions. Food Research International, 112, 307-316.
Published
05-12-2024
Issue
Vol. 4 Issue 2 (2024): JOBC: Journal of Biobased Chemicals
Pages
140-154
License
Copyright (c) 2024 JOBC: Journal of Biobased Chemicals
How to Cite
-